Issue 8, 2019
From the journal:

Chemical Communications

Chiroptical and catalytic properties of doubly binaphthyl-strapped chiral porphyrins†

Chihiro Maeda, ORCID logo *a   Kanae Ogawa,a   Kosuke Sadanaga,a   Kazuto Takaishi ORCID logo a  and  Tadashi Ema ORCID logo *a  

* Corresponding authors

a Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Okayama 700-8530, Japan
E-mail: cmaeda@okayama-u.ac.jp, ema@cc.okayama-u.ac.jp

Abstract

Doubly (R)-binaphthyl-strapped porphyrins with methylene chains were synthesized. The CD spectra showed the positive Cotton effect around the Soret bands, and several porphyrins showed CPL. In addition, we found that the chiral porphyrins were applicable to kinetic resolution of epoxide with CO2.

Graphical abstract: Chiroptical and catalytic properties of doubly binaphthyl-strapped chiral porphyrins

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8CC09114E
Article type
Communication
Submitted
16 Nov 2018
Accepted
12 Dec 2018
First published
13 Dec 2018

Chem. Commun., 2019,55, 1064-1067

Permissions

Request permissions

Chiroptical and catalytic properties of doubly binaphthyl-strapped chiral porphyrins

C. Maeda, K. Ogawa, K. Sadanaga, K. Takaishi and T. Ema, Chem. Commun., 2019, 55, 1064 DOI: 10.1039/C8CC09114E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements