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Issue 22, 2018
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A photocatalytic decarboxylative/defluorinative [4 + 3] annulation of o-hydroxyphenylacetic acids and trifluoromethyl alkenes: synthesis of fluorinated dihydrobenzoxepines

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Abstract

A photocatalytic decarboxylative/defluorinative [4 + 3] annulation of o-hydroxyphenylacetic acids and trifluoromethyl alkenes was developed. The reaction affords fluorinated dihydrobenzoxepines via two consecutive C–F substitutions in a CF3 group.

Graphical abstract: A photocatalytic decarboxylative/defluorinative [4 + 3] annulation of o-hydroxyphenylacetic acids and trifluoromethyl alkenes: synthesis of fluorinated dihydrobenzoxepines

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Publication details

The article was received on 06 Sep 2018, accepted on 29 Sep 2018 and first published on 29 Sep 2018


Article type: Research Article
DOI: 10.1039/C8QO00970H
Citation: Org. Chem. Front., 2018,5, 3240-3244
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    A photocatalytic decarboxylative/defluorinative [4 + 3] annulation of o-hydroxyphenylacetic acids and trifluoromethyl alkenes: synthesis of fluorinated dihydrobenzoxepines

    H. Chen, Y. He and L. Zhou, Org. Chem. Front., 2018, 5, 3240
    DOI: 10.1039/C8QO00970H

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