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Issue 22, 2018
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Oxidative ring-opening of 3-aminoindazoles for the synthesis of 2-aminobenzoates

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Abstract

The first oxidative ring-opening of 3-aminoindazoles based on N–N bond cleavage is reported herein. A variety of 2-aminobenzoates were obtained in good yields under mild conditions, in which the free, mono- and dual-brominated aminobenzoates could be controllably achieved by employing the appropriate oxidant and bromine source.

Graphical abstract: Oxidative ring-opening of 3-aminoindazoles for the synthesis of 2-aminobenzoates

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Publication details

The article was received on 14 Aug 2018, accepted on 26 Sep 2018 and first published on 26 Sep 2018


Article type: Research Article
DOI: 10.1039/C8QO00872H
Citation: Org. Chem. Front., 2018,5, 3245-3249
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    Oxidative ring-opening of 3-aminoindazoles for the synthesis of 2-aminobenzoates

    Y. Zhou and Q. Song, Org. Chem. Front., 2018, 5, 3245
    DOI: 10.1039/C8QO00872H

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