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Issue 22, 2018
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Copper-catalyzed decarboxylative and oxidative decarbonylative cross-coupling between cinnamic acids and aliphatic aldehydes

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Abstract

A copper-catalyzed decarboxylative and oxidative decarbonylative cross-coupling of cinnamic acids with aliphatic aldehydes was achieved. The reaction undergoes subsequent decarbonylation, radical addition and decarboxylation processes with aliphatic aldehydes as the cheap and abundant alkyl radical source. This procedure offers a complementary approach to the convenient generation of alkyl-substituted E-alkenes.

Graphical abstract: Copper-catalyzed decarboxylative and oxidative decarbonylative cross-coupling between cinnamic acids and aliphatic aldehydes

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Publication details

The article was received on 26 Aug 2018, accepted on 06 Oct 2018 and first published on 08 Oct 2018


Article type: Research Article
DOI: 10.1039/C8QO00927A
Citation: Org. Chem. Front., 2018,5, 3299-3305

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    Copper-catalyzed decarboxylative and oxidative decarbonylative cross-coupling between cinnamic acids and aliphatic aldehydes

    Z. Luo, X. Han, Y. Fang, P. Liu, C. Feng, Z. Li and X. Xu, Org. Chem. Front., 2018, 5, 3299
    DOI: 10.1039/C8QO00927A

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