A pillar[5]arene-calix[4]pyrrole enantioselective receptor for mandelate anion recognition

Yongjun Lv; Chao Xiao; Cheng Yang

doi:10.1039/C8NJ04802A

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A pillar[5]arene-calix[4]pyrrole enantioselective receptor for mandelate anion recognition†

Yongjun Lv,

*^a Chao Xiao^b and Cheng Yang

*^b

Author affiliations

* Corresponding authors

^a Material Corrosion and Protection Key Laboratory of Sichuan Province, College of Chemical Engineering, Sichuan University of Science & Engineering, Zigong 643000, China
E-mail: yongjunlv@qq.com

^b Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, State Key Laboratory of Biotherapy, and Healthy Food Evaluation Research Center, Sichuan University, Chengdu 610064, China
E-mail: yangchengyc@scu.edu.cn

Abstract

A novel pillar[5]arene-calix[4]pyrrole macrocyclic compound (PC) featuring anion recognition and host–guest properties was designed and synthesized. This novel macrocycle receptor can be enantioseparated into planar chiral enantiomers that bind R- and S-mandelate guests with an enantioselectivity factor of 2.47.

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Supplementary files

Supplementary information PDF (718K)

Article information

DOI: https://doi.org/10.1039/C8NJ04802A
Article type: Letter
Submitted: 21 Sep 2018
Accepted: 10 Nov 2018
First published: 14 Nov 2018

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New J. Chem., 2018,42, 19357-19359

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A pillar[5]arene-calix[4]pyrrole enantioselective receptor for mandelate anion recognition

Y. Lv, C. Xiao and C. Yang, New J. Chem., 2018, 42, 19357 DOI: 10.1039/C8NJ04802A

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New Journal of Chemistry

A pillar[5]arene-calix[4]pyrrole enantioselective receptor for mandelate anion recognition†

Abstract

Supplementary files

Article information

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A pillar[5]arene-calix[4]pyrrole enantioselective receptor for mandelate anion recognition

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