Iodine-catalyzed diamination of styrene in water with the oxidation of H2O2

Liyan Liu; Qi Sun; Zicong Yan; Xinping Liang; Zhenggen Zha; Yu Yang; Zhiyong Wang

doi:10.1039/C8GC01332B

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Iodine-catalyzed diamination of styrene in water with the oxidation of H₂O₂†

Liyan Liu,‡^a Qi Sun,‡^a Zicong Yan,^a Xinping Liang,^a Zhenggen Zha,^a Yu Yang*^a and Zhiyong Wang

*^a

Author affiliations

* Corresponding authors

^a Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry & Center for Excellence in Molecular Synthesis of Chinese Academy of Sciences, Collaborative Innovation Center of Suzhou Nano Science and Technology & School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui, P. R. China
E-mail: zwang3@ustc.edu.cn
Fax: (+86) 551-360-3185

Abstract

An environmentally friendly diamination was developed in the presence of TMDAI/H₂O₂ with water as the only by-product. A series of 3-amino indolines can be obtained in good to excellent yields. The reaction conditions are very mild and no any organic solvent or metal was involved in the reaction.

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Article information

DOI: https://doi.org/10.1039/C8GC01332B
Article type: Communication
Submitted: 27 Apr 2018
Accepted: 30 Jul 2018
First published: 31 Jul 2018

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Green Chem., 2018,20, 3927-3930

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Iodine-catalyzed diamination of styrene in water with the oxidation of H₂O₂

L. Liu, Q. Sun, Z. Yan, X. Liang, Z. Zha, Y. Yang and Z. Wang, Green Chem., 2018, 20, 3927 DOI: 10.1039/C8GC01332B

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