Tunable mixed oxides based on CeO2 for the selective aerobic oxidation of 5-(hydroxymethyl)furfural to FDCA in water

Maria Ventura; Francesco Nocito; Elvira de Giglio; Stefania Cometa; Angela Altomare; Angela Dibenedetto

doi:10.1039/C8GC00972D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Tunable mixed oxides based on CeO₂ for the selective aerobic oxidation of 5-(hydroxymethyl)furfural to FDCA in water†

Maria Ventura,^a Francesco Nocito,^b Elvira de Giglio,^b Stefania Cometa,^d Angela Altomare^e and Angela Dibenedetto

*^abc

Author affiliations

* Corresponding authors

^a CIRCC, Via Celso Ulpiani, 27, 70126 Bari, Italy

^b Department of Chemistry, UniBari, Campus Universitario, 70126 Bari, Italy
E-mail: angela.dibenedetto@uniba.it

^c IC2R, Viale Einaudi 25, 70125 Bari, Italy

^d Jaber Innovation srl, Via Calcutta 8, Rome, Italy

^e Crystallography Institute-CNR, Via Giovanni Amendola, 122/O, 70126 Bari, Italy

Abstract

Chemicals derived from 5-HMF, via selective oxidation of its pending arms are becoming increasingly important due to their applications. This paper discusses the use of Earth crust abundant new mixed oxides based on CeO₂ able to perform the selective oxidation of 5-HMF to 2,5-furandicarboxylic acid (99%), in water, using oxygen as the oxidant.

Download options Please wait...

Supplementary files

Supplementary information PDF (1258K)

Article information

DOI: https://doi.org/10.1039/C8GC00972D
Article type: Communication
Submitted: 27 Mar 2018
Accepted: 31 Jul 2018
First published: 31 Jul 2018

Download Citation

Green Chem., 2018,20, 3921-3926

Permissions

Request permissions

Tunable mixed oxides based on CeO₂ for the selective aerobic oxidation of 5-(hydroxymethyl)furfural to FDCA in water

M. Ventura, F. Nocito, E. de Giglio, S. Cometa, A. Altomare and A. Dibenedetto, Green Chem., 2018, 20, 3921 DOI: 10.1039/C8GC00972D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Green Chemistry