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Issue 81, 2018
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Cyanomethyl anion transfer reagents for diastereoselective Corey–Chaykovsky cyclopropanation reactions

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Abstract

A readily available and bench-stable cyanomethyl sulfonium salt was used in highly diastereoselective Corey–Chaykovsky cyclopropanation reactions of electron-poor olefins. This efficient method provides a rapid route to access densely functionalized cyclopropyl nitriles.

Graphical abstract: Cyanomethyl anion transfer reagents for diastereoselective Corey–Chaykovsky cyclopropanation reactions

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Publication details

The article was received on 11 Jul 2018, accepted on 20 Sep 2018 and first published on 20 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC05602A
Chem. Commun., 2018,54, 11439-11442

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    Cyanomethyl anion transfer reagents for diastereoselective Corey–Chaykovsky cyclopropanation reactions

    R. Hommelsheim, K. J. Hock, C. Schumacher, M. A. Hussein, T. V. Nguyen and R. M. Koenigs, Chem. Commun., 2018, 54, 11439
    DOI: 10.1039/C8CC05602A

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