Issue 57, 2018

An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source

Abstract

Hydroaminomethylation of olefins with H2O as the hydrogen source was accomplished over an Ir-catalyst with the involvement of an ionic diphosphine (L6). The use of H2O as the hydrogen source could completely inhibit the hydrogenation of olefins. The π-accepting ability and improved stability of L6 endowed the corresponding Ir-catalyst with high activity and good longevity for recycling uses.

Graphical abstract: An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source

Associated articles

Supplementary files

Article information

Article type
Communication
Submitted
27 Apr 2018
Accepted
15 Jun 2018
First published
19 Jun 2018

Chem. Commun., 2018,54, 7979-7982

An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source

H. Liu, D. Yang, D. Wang, P. Wang, Y. Lu, V. Giang and Y. Liu, Chem. Commun., 2018, 54, 7979 DOI: 10.1039/C8CC03431A

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