Metal sulfides are an excellent material group for highly efficient water reduction to H2. We demonstrate the uphill reaction using a single-particulate metal sulfide photocatalyst. A Ru cocatalyst-loaded ZnS photocatalyst showed an activity for the decomposition of an aqueous solution into H2 and N2 under simulated sunlight irradiation.
A. Iwase, K. Ii and A. Kudo, Chem. Commun., 2018, 54, 6117 DOI: 10.1039/C8CC02639D
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