Issue 21, 2017
From the journal:

Chemical Communications

Palladium-catalysed intramolecular carbenoid insertion of α-diazo-α-(methoxycarbonyl)acetanilides for oxindole synthesis†

Daniel Solé, ORCID logo *a   Ferran Pérez-Janera  and  Israel Fernández ORCID logo *b  

* Corresponding authors

a Laboratori de Química Orgànica, Facultat de Farmàcia, Universitat de Barcelona, Av. Joan XXIII 27-31, 08028 Barcelona, Spain
E-mail: dsole@ub.edu

b Departamento de Química Orgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040 Madrid, Spain
E-mail: israel@quim.ucm.es

Abstract

A novel, selective palladium-catalysed carbenoid C(aryl)–H insertion of α-diazo-α-(methoxycarbonyl)acetanilides leading to oxindoles is described.

Graphical abstract: Palladium-catalysed intramolecular carbenoid insertion of α-diazo-α-(methoxycarbonyl)acetanilides for oxindole synthesis

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Article information

DOI
https://doi.org/10.1039/C7CC00718C
Article type
Communication
Submitted
25 Jan 2017
Accepted
24 Feb 2017
First published
24 Feb 2017

Chem. Commun., 2017,53, 3110-3113

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Palladium-catalysed intramolecular carbenoid insertion of α-diazo-α-(methoxycarbonyl)acetanilides for oxindole synthesis

D. Solé, F. Pérez-Janer and I. Fernández, Chem. Commun., 2017, 53, 3110 DOI: 10.1039/C7CC00718C

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