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Issue 32, 2017
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Pyreneacyl sulfides as a visible light-induced versatile ligation platform

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Abstract

We report a visible light responsive moiety capable of generating highly reactive thioaldehydes. Upon irradiation with visible light (420 nm) the pyreneacyl sulfide species undergoes a Norrish II elimination yielding thioaldehydes capable of being trapped by nucleophiles (amines, aminoxys, and thiols), as well as Diels–Alder processes, representing a new versatile ligation platform.

Graphical abstract: Pyreneacyl sulfides as a visible light-induced versatile ligation platform

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Article information


Submitted
25 Jan 2017
Accepted
28 Mar 2017
First published
28 Mar 2017

Chem. Commun., 2017,53, 4501-4504
Article type
Communication

Pyreneacyl sulfides as a visible light-induced versatile ligation platform

B. T. Tuten, J. P. Menzel, K. Pahnke, J. P. Blinco and C. Barner-Kowollik, Chem. Commun., 2017, 53, 4501
DOI: 10.1039/C7CC00711F

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