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Issue 19, 2017
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Non-sensitized selective photochemical reduction of CO2 to CO under visible light with an iron molecular catalyst

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Abstract

A substituted tetraphenyl iron porphyrin, bearing positively charged trimethylammonio groups at the para position of each phenyl ring, demonstrates its ability as a homogeneous molecular catalyst to selectively reduce CO2 to CO under visible light irradiation in organic media without the assistance of a sensitizer and no competitive hydrogen evolution for several days.

Graphical abstract: Non-sensitized selective photochemical reduction of CO2 to CO under visible light with an iron molecular catalyst

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Publication details

The article was received on 15 Dec 2016, accepted on 13 Feb 2017 and first published on 13 Feb 2017


Article type: Communication
DOI: 10.1039/C6CC09967J
Citation: Chem. Commun., 2017,53, 2830-2833

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    Non-sensitized selective photochemical reduction of CO2 to CO under visible light with an iron molecular catalyst

    H. Rao, J. Bonin and M. Robert, Chem. Commun., 2017, 53, 2830
    DOI: 10.1039/C6CC09967J

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