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Issue 12, 2017
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Metal-induced supramolecular chirality inversion of small self-assembled molecules in solution

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Abstract

A non-covalent self-assembled chiral alanyl aminopyridine ligand exhibits supramolecular chirality in solution, independent of the organic solvent used. The supramolecular chirality of the assemblies is completely inverted by complexation to zinc ions. To date, such a supramolecular metal–ligand system has not been reported in the literature.

Graphical abstract: Metal-induced supramolecular chirality inversion of small self-assembled molecules in solution

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Supplementary files

Article information


Submitted
17 Nov 2016
Accepted
11 Jan 2017
First published
11 Jan 2017

Chem. Commun., 2017,53, 1945-1948
Article type
Communication

Metal-induced supramolecular chirality inversion of small self-assembled molecules in solution

Z. Kokan, B. Perić, M. Vazdar, Ž. Marinić, D. Vikić-Topić, E. Meštrović and S. I. Kirin, Chem. Commun., 2017, 53, 1945
DOI: 10.1039/C6CC09203A

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