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Issue 1, 2017
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Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

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Abstract

The chiral expression of a molecule on a surface is driven from a random solid solution on Cu(100) to a racemic crystal on a Sn/Cu(100) alloy. Density functional theory simulations reveal how the growth of the racemate is influenced by the underlying surface.

Graphical abstract: Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

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Publication details

The article was received on 18 Aug 2016, accepted on 29 Nov 2016 and first published on 29 Nov 2016


Article type: Communication
DOI: 10.1039/C6CC06785A
Citation: Chem. Commun., 2017,53, 130-133
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    Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

    J. D. Fuhr, M. W. van der Meijden, L. J. Cristina, L. M. Rodríguez, R. M. Kellogg, J. E. Gayone, H. Ascolani and M. Lingenfelder, Chem. Commun., 2017, 53, 130
    DOI: 10.1039/C6CC06785A

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