Issue 45, 2016, Issue in Progress

Synergistic effect between Pd and Re on Pd–Re/SBA-15 catalysts and their catalytic behavior in glycerol hydrogenolysis

Abstract

Pd–Re/SBA-15 catalysts were prepared by the impregnation method. The influence of the interaction between Pd and Re in the Pd–Re catalysts on glycerol hydrogenolysis was investigated. Pd and Re had interaction which was confirmed by H2-TPR, XPS and EXAFS. In the Pd–Re catalysts, Re showed a higher oxidation state compared with that of the mono-component Re catalyst. The mechanically mixed Pd + Re catalysts showed a lower glycerol conversion than that of the bi-component Pd–Re catalysts, which suggested that the interaction of Pd and Re was very important in glycerol hydrogenolysis.

Graphical abstract: Synergistic effect between Pd and Re on Pd–Re/SBA-15 catalysts and their catalytic behavior in glycerol hydrogenolysis

Supplementary files

Article information

Article type
Paper
Submitted
30 Jan 2016
Accepted
01 Apr 2016
First published
05 Apr 2016

RSC Adv., 2016,6, 38680-38689

Author version available

Synergistic effect between Pd and Re on Pd–Re/SBA-15 catalysts and their catalytic behavior in glycerol hydrogenolysis

Y. Li, H. Liu, L. Ma and D. He, RSC Adv., 2016, 6, 38680 DOI: 10.1039/C6RA02758J

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