Jump to main content
Jump to site search

Issue 26, 2016
Previous Article Next Article

Metal free TBHP-promoted intramolecular carbonylation of arenes via radical cross-dehydrogenative coupling: synthesis of indenoquinolinones, 4-azafluorenones and fluorenones

Author affiliations

Abstract

A metal-free, TBHP-promoted economical route is developed via the sp2 C–H bond functionalization strategy for the synthesis of indenoquinolinones, 4-azafluorenones and fluorenones. Reactions provided excellent yield of the products under mild conditions. We have successfully synthesized 11H-indeno[1,2-b]quinolin-11-one, an antibacterial agent, in excellent yields.

Graphical abstract: Metal free TBHP-promoted intramolecular carbonylation of arenes via radical cross-dehydrogenative coupling: synthesis of indenoquinolinones, 4-azafluorenones and fluorenones

Back to tab navigation

Supplementary files

Publication details

The article was received on 07 May 2016, accepted on 27 May 2016 and first published on 07 Jun 2016


Article type: Paper
DOI: 10.1039/C6OB00998K
Org. Biomol. Chem., 2016,14, 6328-6336

  •   Request permissions

    Metal free TBHP-promoted intramolecular carbonylation of arenes via radical cross-dehydrogenative coupling: synthesis of indenoquinolinones, 4-azafluorenones and fluorenones

    K. Mishra, A. K. Pandey, J. B. Singh and R. M. Singh, Org. Biomol. Chem., 2016, 14, 6328
    DOI: 10.1039/C6OB00998K

Search articles by author

Spotlight

Advertisements