Jump to main content
Jump to site search

Issue 5, 2016
Previous Article Next Article

Stereoselective synthesis of β-rhamnopyranosides via gold(I)-catalyzed glycosylation with 2-alkynyl-4-nitro-benzoate donors

Author affiliations

Abstract

Stereoselective β-rhamnopyranosylation remains a challenge, due to the unfavorable anomeric effect and steric hindrance of the C2-substituent; herein, this challenge is addressed with a gold(I)-catalyzed SN2-like glycosylation protocol employing α-rhamnopyranosyl 2-alkynyl-4-nitro-benzoates as donors.

Graphical abstract: Stereoselective synthesis of β-rhamnopyranosides via gold(i)-catalyzed glycosylation with 2-alkynyl-4-nitro-benzoate donors

Back to tab navigation

Supplementary files

Publication details

The article was received on 17 Nov 2015, accepted on 15 Dec 2015 and first published on 15 Dec 2015


Article type: Communication
DOI: 10.1039/C5OB02551F
Citation: Org. Biomol. Chem., 2016,14, 1536-1539
  •   Request permissions

    Stereoselective synthesis of β-rhamnopyranosides via gold(I)-catalyzed glycosylation with 2-alkynyl-4-nitro-benzoate donors

    Y. Zhu, Z. Shen, W. Li and B. Yu, Org. Biomol. Chem., 2016, 14, 1536
    DOI: 10.1039/C5OB02551F

Search articles by author

Spotlight

Advertisements