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Issue 3, 2016
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Zn/Sc bimetallic relay catalysis: one pot cycloisomerization/carbonyl–ene reaction toward oxazole derivatives

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Abstract

A novel tandem metal relay catalytic system combining Zn(II)-catalyzed cycloisomerization and a Sc(III)-catalyzed carbonyl–ene reaction has been successfully developed. By using this unprecedented Zn/Sc bimetallic relay catalytic system, a variety of oxazole derivatives were obtained from easily available N-(propargyl)arylamides and aldehydes under mild conditions.

Graphical abstract: Zn/Sc bimetallic relay catalysis: one pot cycloisomerization/carbonyl–ene reaction toward oxazole derivatives

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Article information


Submitted
19 Oct 2015
Accepted
16 Nov 2015
First published
17 Nov 2015

Org. Biomol. Chem., 2016,14, 826-829
Article type
Communication
Author version available

Zn/Sc bimetallic relay catalysis: one pot cycloisomerization/carbonyl–ene reaction toward oxazole derivatives

B. Wang, Y. Chen, L. Zhou, J. Wang and Z. Xu, Org. Biomol. Chem., 2016, 14, 826
DOI: 10.1039/C5OB02158H

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