Issue 32, 2016
From the journal:

Dalton Transactions

A nonanuclear triangular macrocycle and a linear heptanuclear heterometallic complex based on a 2-substituted imidazole-4,5-dicarboxylate ligand†‡

Yue-Jian Lin,§a   Wei-Long Shan§a  and  Guo-Xin Jin*a  

* Corresponding authors

a State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China
E-mail: gxjin@fudan.edu.cn

Abstract

A Cp*Rh-based nonanuclear triangular macrocycle complex [(Cp*Rh)9L3(NO3)4.5(MeOH)](OTf)4.5 (1), a Cp*Ir-based trinuclear complex [(Cp*Ir)3L(MeCN)4](OTf)3 (2) and a linear heptanuclear heterometallic complex [(Cp*Ir)6ZnL2(MeCN)8(MeOH)2](OTf)8 (3) (Cp* = η5-pentamethylcyclopentadienyl) have been synthesized from a 2-(4-(pyridin-4-yl)phenyl)-1H-imidazole-4,5-dicarboxylic acid proligand. These complexes were further characterized by X-ray crystallography, 1H NMR, DOSY NMR, IR spectroscopy, and elemental analyses.

Graphical abstract: A nonanuclear triangular macrocycle and a linear heptanuclear heterometallic complex based on a 2-substituted imidazole-4,5-dicarboxylate ligand

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Article information

DOI
https://doi.org/10.1039/C6DT02460B
Article type
Paper
Submitted
20 Jun 2016
Accepted
21 Jul 2016
First published
22 Jul 2016

Dalton Trans., 2016,45, 12680-12684

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A nonanuclear triangular macrocycle and a linear heptanuclear heterometallic complex based on a 2-substituted imidazole-4,5-dicarboxylate ligand

Y. Lin, W. Shan and G. Jin, Dalton Trans., 2016, 45, 12680 DOI: 10.1039/C6DT02460B

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