Issue 29, 2016
From the journal:

Dalton Transactions

A novel oxime-derived 3d–4f single-molecule magnet exhibiting two single-ion magnetic relaxations†

Hui-Ming Dong,a   Yan Li,b   Zhong-Yi Liu,b   En-Cui Yang*b  and  Xiao-Jun Zhao*ab  

* Corresponding authors

a Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, People's Republic of China
E-mail: xiaojun_zhao15@163.com
Fax: +86-22-23766556

b College of Chemistry, Key Laboratory of Inorganic–Organic Hybrid Functional Material Chemistry, Ministry of Education, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, People's Republic of China
E-mail: encui_yang@163.com

Abstract

A new oxime-derived {DyIII4NiII6} cluster with a paramagnetic butterfly-shaped DyIII4 core and peripheral diamagnetic planar-square NiII ions was solvothermally synthesized. The weak ferromagnetically coupled cluster exhibits field-induced single-molecule magnetic behavior with two thermally activated single-ion relaxations.

Graphical abstract: A novel oxime-derived 3d–4f single-molecule magnet exhibiting two single-ion magnetic relaxations

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Article information

DOI
https://doi.org/10.1039/C6DT02003H
Article type
Paper
Submitted
19 May 2016
Accepted
21 Jun 2016
First published
22 Jun 2016

Dalton Trans., 2016,45, 11876-11882

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A novel oxime-derived 3d–4f single-molecule magnet exhibiting two single-ion magnetic relaxations

H. Dong, Y. Li, Z. Liu, E. Yang and X. Zhao, Dalton Trans., 2016, 45, 11876 DOI: 10.1039/C6DT02003H

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