Issue 97, 2016
From the journal:

Chemical Communications

A pendant phosphorus Lewis acid: route to a palladium-benzoyl derived phosphorane†

Kelly F. Firth,a   Juri Möbusa  and  Douglas W. Stephan*a  

* Corresponding authors

a Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, Canada
E-mail: dstephan@chem.utoronto.ca

Abstract

The traditional use of phosphorus compounds is as ligands for transition metals, however herein we synthesize Lewis acidic fluorophosphonium cation appended to a palladium complex and effect CO insertion into a Pd–C bond to obtain an unprecedented metal-benzoyl derived phosphorane.

Graphical abstract: A pendant phosphorus Lewis acid: route to a palladium-benzoyl derived phosphorane

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Article information

DOI
https://doi.org/10.1039/C6CC08561J
Article type
Communication
Submitted
24 Oct 2016
Accepted
10 Nov 2016
First published
10 Nov 2016

Chem. Commun., 2016,52, 13967-13970

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A pendant phosphorus Lewis acid: route to a palladium-benzoyl derived phosphorane

K. F. Firth, J. Möbus and D. W. Stephan, Chem. Commun., 2016, 52, 13967 DOI: 10.1039/C6CC08561J

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