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Issue 64, 2016
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Intramolecular cooperativity in frustrated Lewis pairs

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Abstract

The doubly Lewis-acid functionalised aniline PhN[(CH2)3B(C6F5)2]2 features two competing boron functions in fast exchange for binding to the central Lewis base. It shows catalytic activity typical for FLPs in H/D-scrambling and catalytic hydrogenation experiments. By contrast, the singly acid-functionalised PhMeN(CH2)3B(C6F5)2 reveals a dramatically smaller catalytic activity in analogous experiments.

Graphical abstract: Intramolecular cooperativity in frustrated Lewis pairs

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Publication details

The article was received on 22 Jun 2016, accepted on 27 Jun 2016 and first published on 14 Jul 2016


Article type: Communication
DOI: 10.1039/C6CC05228B
Citation: Chem. Commun., 2016,52, 9949-9952

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    Intramolecular cooperativity in frustrated Lewis pairs

    L. A. Körte, S. Blomeyer, S. Heidemeyer, A. Mix, B. Neumann and N. W. Mitzel, Chem. Commun., 2016, 52, 9949
    DOI: 10.1039/C6CC05228B

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