Solvent- and anion-induced interconversions of metal–organic cages

Yu-Hao Li; Ji-Jun Jiang; Yan-Zhong Fan; Zhang-Wen Wei; Cheng-Xia Chen; Hui-Juan Yu; Shao-Ping Zheng; Dieter Fenske; Cheng-Yong Su; Mihail Barboiu

doi:10.1039/C6CC04420D

Solvent- and anion-induced interconversions of metal–organic cages†

Yu-Hao Li,^a Ji-Jun Jiang,^a Yan-Zhong Fan,^a Zhang-Wen Wei,^a Cheng-Xia Chen,^a Hui-Juan Yu,^a Shao-Ping Zheng,^a Dieter Fenske,^a Cheng-Yong Su

*^a and Mihail Barboiu*^ab

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* Corresponding authors

^a MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: cesscy@mail.sysu.edu.cn

^b Adaptive Supramolecular Nanosystems Group, Institut Europeen des Membranes, University of Montpellier ENSCM-UMR CNRS 5635, Place Eugene Bataillon CC047, Montpellier, France
E-mail: mihail-dumitru.barboiu@univ-montp2.fr

Abstract

Fully structural interconversions between monomeric Pd₂L₄ and interlocked dimeric Pd₄L₈ cages have been investigated to elucidate their thermodynamic stability defined by their anion-guest binding behaviours.

Chemical Communications

Solvent- and anion-induced interconversions of metal–organic cages†

Abstract

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Solvent- and anion-induced interconversions of metal–organic cages

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