SCHEDULED MAINTENANCE
The reversible switching of a sterically encumbered phenanthroline–Cu+–picolinaldehyde trio back and forth between homoleptic and heteroleptic coordination using the relative metal-ion to ligand ratio is the basis for an unprecedented cyclic three-state interconversion of metallacycles.
N. Mittal, M. L. Saha and M. Schmittel, Chem. Commun., 2016, 52, 8749 DOI: 10.1039/C6CC03824G
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