Issue 4, 2016
From the journal:

Chemical Communications

Improved synthesis of trigone trimer cluster metal organic framework MIL-100Al by a later entry of methyl groups†

Jiangfeng Yang,a   Jun Wang,b   Shuguang Deng*b  and  Jinping Li*a  

* Corresponding authors

a Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China
E-mail: jpli211@hotmail.com

b Arizona State University, School for Engineering of Matter, Transport & Energy, 551 E. Tyler Mall, Tempe, AZ 85287, USA
E-mail: Shuguang.Deng@asu.edu

Abstract

Later entry of methyl or ethyl groups was carried out for the economical synthesis of trigone trimer cluster MIL-100Al oriented from H3BTC directly. The pure phase MIL-100Al was obtained in a DMF aqueous solution, and equal amounts of methyl and carboxyl groups are the key for the successful synthesis of MIL-100Al.

Graphical abstract: Improved synthesis of trigone trimer cluster metal organic framework MIL-100Al by a later entry of methyl groups

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Article information

DOI
https://doi.org/10.1039/C5CC08450D
Article type
Communication
Submitted
12 Oct 2015
Accepted
26 Oct 2015
First published
26 Oct 2015

Chem. Commun., 2016,52, 725-728

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Improved synthesis of trigone trimer cluster metal organic framework MIL-100Al by a later entry of methyl groups

J. Yang, J. Wang, S. Deng and J. Li, Chem. Commun., 2016, 52, 725 DOI: 10.1039/C5CC08450D

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