Issue 4, 2016
From the journal:

Chemical Communications

Direct heptafluoroisopropylation of arylboronic acids via hexafluoropropene (HFP)†

Yajun Li,ab   Xiaojun Wang,ac   Yuwei Guo,ac   Zhentong Zhu,ad   Yongming Wu*a  and  Yuefa Gong*b  

* Corresponding authors

a Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
E-mail: ymwu@sioc.ac.cn

b School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan 430074, China
E-mail: gongyf@mail.hust.edu.cn

c Department of Chemistry, Shanghai University, 99 Shangda Road, Shanghai 200444, China

d School of Chemical and Environmental Engineering, Shanghai Institute of Technology, 100 Haiquan Road, Shanghai 201418, China

Abstract

A novel and straightforward strategy for heptafluoroisopropylation of arylboronic acids at room temperature has been developed. This method, directly using commercial available hexafluoropropene (HFP) as the starting material, provides a new way to synthesize a variety of synthetically useful heptafluoroisopropylated arenes.

Graphical abstract: Direct heptafluoroisopropylation of arylboronic acids via hexafluoropropene (HFP)

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Article information

DOI
https://doi.org/10.1039/C5CC07616A
Article type
Communication
Submitted
11 Sep 2015
Accepted
05 Nov 2015
First published
06 Nov 2015

Chem. Commun., 2016,52, 796-799

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Direct heptafluoroisopropylation of arylboronic acids via hexafluoropropene (HFP)

Y. Li, X. Wang, Y. Guo, Z. Zhu, Y. Wu and Y. Gong, Chem. Commun., 2016, 52, 796 DOI: 10.1039/C5CC07616A

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