Issue 56, 2015
From the journal:

RSC Advances

Amine-catalyzed cascade reactions of ketoses with 1,3-dicarbonyl compounds†

Celin Richter,a   Benjamin Voigta  and  Rainer Mahrwald*a  

* Corresponding authors

a Humboldt-University, Institute of Chemistry, Brook-Taylor Str. 2, 12489 Berlin, Germany
E-mail: rainer.mahrwald@rz.hu-berlin.de

Abstract

An amine-catalyzed cascade reaction of ketoses with 1,3-dicarbonyl compounds is described. Several highly chemo- as well as stereoselective reactions are operating in this novel cascade. The operationally simple protocol allows stereoselective access to optically active carbon chain elongated ketoses.

Graphical abstract: Amine-catalyzed cascade reactions of ketoses with 1,3-dicarbonyl compounds

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Article information

DOI
https://doi.org/10.1039/C5RA08757K
Article type
Communication
Submitted
01 Apr 2015
Accepted
14 May 2015
First published
14 May 2015

RSC Adv., 2015,5, 45571-45574

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Amine-catalyzed cascade reactions of ketoses with 1,3-dicarbonyl compounds

C. Richter, B. Voigt and R. Mahrwald, RSC Adv., 2015, 5, 45571 DOI: 10.1039/C5RA08757K

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