Unimolecular initiator end-capped and anchored dendrimers with an initiator functionality of up to 48 for G4 dendrimer were prepared quantitatively in a single-step reaction. Polymerization of styrene using these initiators yielded multi arm star polymers with mol. weight (Mw) in the order of 105 g mol−1 and polydispersity of arm in the range of 1.01 to 1.09.
S. Veerapandian and A. Sultan Nasar, RSC Adv., 2015, 5, 23034 DOI: 10.1039/C5RA02352A
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