SCHEDULED MAINTENANCE
Two concise routes for the first total synthesis of Sparstolonin B (SsnB) have been described. The synthesis of SsnB could be accomplished in 5 and 6 steps with 40% and 38% overall yield, respectively. The rhodium-catalysed oxidative coupling of benzoic acid with internal alkyne was used in both strategies to construct the core structure of SsnB.
Y. Wang, C. Wang, Y. Wang, L. Dong and J. Sun, RSC Adv., 2015, 5, 12354 DOI: 10.1039/C4RA15948A
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