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Issue 20, 2015
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Soluble bipolar star-shaped molecule as highly stable and efficient blue light emitter

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Abstract

A star-shaped blue small-molecule 1,3,5-tris(5-(4-(3,6-di-tert-butylcarbazol-9-yl)phenyl)-1,3,4-oxadiazol-2-yl)benzene (S-Cz-OXD) with donor–π–acceptor (D–π–A) structure was designed and synthesized by incorporating three (3,6-di-tert-butyl-9H-carbazol-9-yl)phenyl arms into an tris(1,3,4-oxadiazole)phenylene core. It gives pure blue photoluminescence emission at 424 nm with high quantum efficiency (Φf) (93%) in dilute toluene and has good solubility in common solvents. This star-shaped molecule also demonstrates enhanced Φf (72%) in the film state. Moreover, the spectral stability of S-Cz-OXD is also excellent due to its low lying HOMO level and absence of fluorene moiety. The PL spectrum of S-Cz-OXD remains virtually unchanged even after annealing at 150 °C for 220 hours in air. The solution-processed non-doped electroluminescent device shows a low turn-on voltage of 3.7 V although there exists a big energy barrier due to the bipolar design. The device emits stable pure blue light, CIE (Commission Internationale de L'Eclairage) coordinates of (0.16, 0.16) with high current efficiency (CE) and external quantum efficiency (EQE) of 4.22 cd A−1 and 3.37% respectively. Mechanistic discussion is also carried out in relation to the molecular structure.

Graphical abstract: Soluble bipolar star-shaped molecule as highly stable and efficient blue light emitter

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Article information


Submitted
20 Nov 2014
Accepted
16 Jan 2015
First published
19 Jan 2015

RSC Adv., 2015,5, 15399-15406
Article type
Paper
Author version available

Soluble bipolar star-shaped molecule as highly stable and efficient blue light emitter

X. He, L. Chen, Y. Zhao, S. C. Ng, X. Wang, X. Sun and X. (Matthew) Hu, RSC Adv., 2015, 5, 15399
DOI: 10.1039/C4RA14934C

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