Issue 45, 2015
From the journal:

Organic & Biomolecular Chemistry

Organocatalytic asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones via an intermolecular Diels–Alder reaction†

Ryukichi Takagi*a  and  Takehiko Nishia  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan
E-mail: rtakagi@hiroshima-u.ac.jp
Fax: +81-82-424-0727
Tel: +81-82-424-7434

Abstract

Asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones via a chiral phosphoric acid-catalyzed enantioselective intermolecular Diels–Alder reaction is developed.

Graphical abstract: Organocatalytic asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones via an intermolecular Diels–Alder reaction

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Article information

DOI
https://doi.org/10.1039/C5OB01760B
Article type
Paper
Submitted
24 Aug 2015
Accepted
11 Sep 2015
First published
11 Sep 2015

Org. Biomol. Chem., 2015,13, 11039-11045

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Organocatalytic asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones via an intermolecular Diels–Alder reaction

R. Takagi and T. Nishi, Org. Biomol. Chem., 2015, 13, 11039 DOI: 10.1039/C5OB01760B

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