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Issue 44, 2015
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Enantioselective addition of arylboronic acids to methyl 2-formylbenzoates by using a ruthenium/Me-BIPAM catalyst for synthesis of chiral 3-aryl-isobenzofuranones

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Abstract

Ruthenium/Me-BIPAM-catalyzed asymmetric addition of arylboronic acids to methyl 2-formylbenzoates afforded chiral 3-aryl-isobenzofuranones. [RuCl2(p-cymene)]2/Me-BIPAM and RuCl2(PPh3)3/Me-BIPAM catalyst systems tolerate a variety of functional groups and give high yields with high enantioselectivities.

Graphical abstract: Enantioselective addition of arylboronic acids to methyl 2-formylbenzoates by using a ruthenium/Me-BIPAM catalyst for synthesis of chiral 3-aryl-isobenzofuranones

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Supplementary files

Article information


Submitted
07 Aug 2015
Accepted
07 Sep 2015
First published
07 Sep 2015

Org. Biomol. Chem., 2015,13, 10874-10880
Article type
Paper

Enantioselective addition of arylboronic acids to methyl 2-formylbenzoates by using a ruthenium/Me-BIPAM catalyst for synthesis of chiral 3-aryl-isobenzofuranones

M. Yohda and Y. Yamamoto, Org. Biomol. Chem., 2015, 13, 10874
DOI: 10.1039/C5OB01661D

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