Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 21, 2015
Previous Article Next Article

Copper(II)-catalyzed highly regio- and stereo-selective hydrosilylation of unactivated internal alkynes with silylborate in water

Author affiliations

Abstract

The highly regio- and stereoselective hydrosilylation of internal alkynes with silylborate catalyzed by Cu(OTf)2 with 1,10-phenanthroline as the ligand in the presence of Cs2CO3 in water is developed. This protocol was applied efficiently in the aqueous synthesis of multi-substituted vinylsilanes.

Graphical abstract: Copper(ii)-catalyzed highly regio- and stereo-selective hydrosilylation of unactivated internal alkynes with silylborate in water

Back to tab navigation

Supplementary files

Publication details

The article was received on 07 Apr 2015, accepted on 14 Apr 2015 and first published on 14 Apr 2015


Article type: Communication
DOI: 10.1039/C5OB00694E
Citation: Org. Biomol. Chem., 2015,13, 5871-5874

  •   Request permissions

    Copper(II)-catalyzed highly regio- and stereo-selective hydrosilylation of unactivated internal alkynes with silylborate in water

    Q. Xuan, C. Ren, L. Liu, D. Wang and C. Li, Org. Biomol. Chem., 2015, 13, 5871
    DOI: 10.1039/C5OB00694E

Search articles by author

Spotlight

Advertisements