Issue 13, 2015

Manganese catalysed sulfenylation of N-methyl amides with arenesulfonyl hydrazides

Abstract

A convenient oxidative sulfenylation method for the formation of various sulfenyl amides has been reported. Arenesulfonyl hydrazine as a sulfur source in the presence of a manganese salt can activate the sp3 C–H bond of N-methyl amides through a free-radical pathway using di-tert-butyl peroxide (DTBP).

Graphical abstract: Manganese catalysed sulfenylation of N-methyl amides with arenesulfonyl hydrazides

Supplementary files

Article information

Article type
Communication
Submitted
23 Jan 2015
Accepted
12 Feb 2015
First published
12 Feb 2015

Org. Biomol. Chem., 2015,13, 3878-3881

Author version available

Manganese catalysed sulfenylation of N-methyl amides with arenesulfonyl hydrazides

J. Sun, Y. Wang and Y. Pan, Org. Biomol. Chem., 2015, 13, 3878 DOI: 10.1039/C5OB00133A

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