Issue 3, 2015

Rhodium-catalysed arylative annulation of 1,4-enynes with arylboronic acids

Abstract

The rhodium(I)-catalysed arylative annulation of 1,4-enynes with arylboronic acids was investigated. The reaction was found to proceed via an addition–1,4-rhodium migration–addition sequence, affording the corresponding 1,1-disubstituted 3-(arylmethylene)indanes.

Graphical abstract: Rhodium-catalysed arylative annulation of 1,4-enynes with arylboronic acids

Supplementary files

Article information

Article type
Communication
Submitted
17 Oct 2014
Accepted
17 Nov 2014
First published
18 Nov 2014

Org. Biomol. Chem., 2015,13, 702-705

Author version available

Rhodium-catalysed arylative annulation of 1,4-enynes with arylboronic acids

T. Matsuda and S. Watanuki, Org. Biomol. Chem., 2015, 13, 702 DOI: 10.1039/C4OB02210F

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