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Issue 2, 2016
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Operando XAFS of supported Pd nanoparticles in flowing ethanol/water mixtures: implications for catalysis

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Abstract

Ethanol–water, a prototypical ‘green’ solvent mixture, cannot be considered as inert toward supported Pd nanoparticles. We establish severe size dependencies in Pd redox behavior, persistent gradients in Pd phase in a plug-flow situation, and that Pd nanoparticles are contaminated with hydrogen derived from the solvent.

Graphical abstract: Operando XAFS of supported Pd nanoparticles in flowing ethanol/water mixtures: implications for catalysis

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Publication details

The article was received on 14 Jul 2015, accepted on 07 Aug 2015 and first published on 12 Aug 2015


Article type: Communication
DOI: 10.1039/C5GC01600B
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Green Chem., 2016,18, 406-411
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    Operando XAFS of supported Pd nanoparticles in flowing ethanol/water mixtures: implications for catalysis

    M. A. Newton, J. B. Brazier, E. M. Barreiro, S. Parry, H. Emmerich, L. A. Adrio, C. J. Mulligan, K. Hellgardt and K. K. (. Hii, Green Chem., 2016, 18, 406
    DOI: 10.1039/C5GC01600B

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