Issue 48, 2015
From the journal:

Dalton Transactions

Structural phase transition in a multi-induced mononuclear FeII spin-crossover complex†

Yuan-Yuan Zhu,*a   Chang-Wei Liu,a   Ji Yin,a   Zhao-Sha Meng,b   Qian Yang,b   Junhu Wang,c   Tao Liu*d  and  Song Gao*b  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Hefei University of Technology and Anhui Key Laboratory of Advanced Functional Materials and Devices, Hefei 230009, China
E-mail: yyzhu@hfut.edu.cn

b Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
E-mail: gaosong@pku.edu.cn

c Mössbauer Effect Data Center & Laboratory of Catalysts and New Materials for Aerospace, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China

d State Key Laboratory of Fine Chemicals, Dalian University of Technology, 2 Linggong Road, Dalian, China
E-mail: liutao@dlut.edu.cn

Abstract

Herein, we report the investigation of a mononuclear spin-crossover complex [FeIIL2][ClO4]2 (L = 2,6-bis{4,4-dimethyl-4,5-dihydrooxazol-2-yl}pyridine). This compound undergoes a structural phase transition around 173 K, accompanying with an abrupt spin-transition process. Interestingly, it exhibits a multi-induced spin-crossover behavior mediated by heat, light, pressure and solvent.

Graphical abstract: Structural phase transition in a multi-induced mononuclear FeII spin-crossover complex

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Article information

DOI
https://doi.org/10.1039/C5DT03216D
Article type
Paper
Submitted
20 Aug 2015
Accepted
30 Oct 2015
First published
30 Oct 2015

Dalton Trans., 2015,44, 20906-20912

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Structural phase transition in a multi-induced mononuclear FeII spin-crossover complex

Y. Zhu, C. Liu, J. Yin, Z. Meng, Q. Yang, J. Wang, T. Liu and S. Gao, Dalton Trans., 2015, 44, 20906 DOI: 10.1039/C5DT03216D

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