Issue 28, 2015
From the journal:

Dalton Transactions

Intramolecular cyclization of a diruthenium complex: insight into the mechanism of heteroatom-directed intramolecular C–H/olefin coupling reactions†

Dawei Gong,ab   Bowen Hu,a   Jing Shia  and  Dafa Chen*ac  

* Corresponding authors

a School of Chemical Engineering & Technology, Harbin Institute of Technology, Harbin 150001, P.R. China
E-mail: dafachen@hit.edu.cn

b College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao 266042, P.R. China

c State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071, P.R. China

Abstract

Complex 2, synthesized by the reaction of {(C5H4N)(μ2–η5:η1-C9H5)}Ru3(CO)9 (1) with 1,5-hexadiene, could further transform to another diruthenium complex 3via intramolecular carbometalation. The results are relevant to the mechanism of transition-metal catalyzed heteroatom-directed intramolecular C–H/olefin coupling reactions.

Graphical abstract: Intramolecular cyclization of a diruthenium complex: insight into the mechanism of heteroatom-directed intramolecular C–H/olefin coupling reactions

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Article information

DOI
https://doi.org/10.1039/C5DT02071A
Article type
Communication
Submitted
01 Jun 2015
Accepted
08 Jun 2015
First published
09 Jun 2015

Dalton Trans., 2015,44, 12507-12510

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Intramolecular cyclization of a diruthenium complex: insight into the mechanism of heteroatom-directed intramolecular C–H/olefin coupling reactions

D. Gong, B. Hu, J. Shi and D. Chen, Dalton Trans., 2015, 44, 12507 DOI: 10.1039/C5DT02071A

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