Issue 28, 2015
From the journal:

Dalton Transactions

Discrimination between alkyl and aryl substituents of chiral monoamines by m-phthalic diamide-linked zinc bisporphyrinates†

Xianshi Fang,a   Zhen Han,a   Chenglong Xu,a   Xiaohong Li,a   Yong Wang*a  and  Chuanjiang Hu*ab  

* Corresponding authors

a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P.R. China
E-mail: cjhu@suda.edu.cn

b State Key Lab & Coordination Chemistry Institute, Nanjing University, Nanjing 210093, P. R. China

Abstract

m-Phthalic diamide-linked zinc bisporphyrinates have been developed as chirality probes for monoamines. They are capable of determining the absolute configuration of monoamines and distinguishing between alkyl and aryl substituents of chiral monoamines. Our studies suggest that steric interactions play critical roles in the molecular recognition process.

Graphical abstract: Discrimination between alkyl and aryl substituents of chiral monoamines by m-phthalic diamide-linked zinc bisporphyrinates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5DT01767J
Article type
Communication
Submitted
11 May 2015
Accepted
04 Jun 2015
First published
05 Jun 2015

Dalton Trans., 2015,44, 12511-12515

Author version available

Download author version (PDF)

Permissions

Request permissions

Discrimination between alkyl and aryl substituents of chiral monoamines by m-phthalic diamide-linked zinc bisporphyrinates

X. Fang, Z. Han, C. Xu, X. Li, Y. Wang and C. Hu, Dalton Trans., 2015, 44, 12511 DOI: 10.1039/C5DT01767J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements