Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal–organic framework

Biplab Manna; Aamod V. Desai; Naveen Kumar; Avishek Karmakar; Sujit K. Ghosh

doi:10.1039/C5CE00139K

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Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal–organic framework†

Biplab Manna,^a Aamod V. Desai,^a Naveen Kumar,^a Avishek Karmakar^a and Sujit K. Ghosh

*^a

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^a Department of Chemistry, Indian Institute of Science Education and Research, Dr. Homi Bhabha Road, Pashan, Pune 411008, India
E-mail: sghosh@iiserpune.ac.in
Fax: +91 20 2590 8186
Tel: +91 20 2590 8076

Abstract

A three dimensional (3D) cationic Metal–Organic Framework (MOF) has been fabricated from a neutral N-donor ligand and Cd(ClO₄)₂. The cationic MOF shows guest triggered inherent dynamic behaviour at room temperature. A single-crystal-to-single-crystal (SCSC) transformation experiment enabled the guest dependent structural dynamism to be well understood. The framework also displays facile anion exchange behaviour and anion dependent structural dynamism.

This article is part of the themed collection: Single-Crystal-to-Single-Crystal Transformations

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DOI: https://doi.org/10.1039/C5CE00139K
Article type: Communication
Submitted: 21 Jan 2015
Accepted: 05 Mar 2015
First published: 09 Mar 2015
This article is Open Access

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CrystEngComm, 2015,17, 8796-8800

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Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal–organic framework

B. Manna, A. V. Desai, N. Kumar, A. Karmakar and S. K. Ghosh, CrystEngComm, 2015, 17, 8796 DOI: 10.1039/C5CE00139K

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CrystEngComm

Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal–organic framework†

Abstract

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Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal–organic framework

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