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Issue 88, 2015
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Oxidative addition of carbon–fluorine and carbon–oxygen bonds to Al(i)

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Abstract

Addition of fluoroarenes, fluoroalkanes or benzofuran to [{(2,6-iPr2C6H3NCMe)2CH}Al] results in facile oxidative addition of either a C–F or C–O bond to the Al(I) centre.

Graphical abstract: Oxidative addition of carbon–fluorine and carbon–oxygen bonds to Al(i)

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Article information


Submitted
25 Aug 2015
Accepted
14 Sep 2015
First published
14 Sep 2015

This article is Open Access

Chem. Commun., 2015,51, 15994-15996
Article type
Communication

Oxidative addition of carbon–fluorine and carbon–oxygen bonds to Al(I)

M. R. Crimmin, M. J. Butler and A. J. P. White, Chem. Commun., 2015, 51, 15994
DOI: 10.1039/C5CC07140B

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