Issue 88, 2015
From the journal:

Chemical Communications

Accessing stable zirconium carboxy-aminophosphonate nanosheets as support for highly active Pd nanoparticles†

Ferdinando Costantino,a   Riccardo Vivani,b   Maria Bastianini,a   Luca Ortolani,c   Oriana Piermatti,a   Morena Nocchetti*b  and  Luigi Vaccaro ORCID logo *a  

* Corresponding authors

a CEMIN – Dipartimento di Chimica, Biologia e Biotecnologie University of Perugia, Via Elce di Sotto, 8, 06123 Perugia, Italy
E-mail: luigi.vaccaro@unipg.it
Fax: +39 0755855560

b Dipartimento di Scienze Farmaceutiche, University of Perugia, Via del Liceo 1, 06123 Perugia, Italy
E-mail: morena.nocchetti@unipg.it
Fax: +39 0755855626

c CNR IMM-Bologna, Via Gobetti, 101, 40129 Bologna, Italy

Abstract

Thin nanosheets from a layered zirconium phosphate–carboxyphosphonate is reported here. Small Pd nanoparticles have been supported on these nanosheets by an efficient method. The resulting Pd-catalyst was fully characterized and tested in the Suzuki–Miyaura coupling. The catalytic system proved its efficiency as it was reused for several cycles and showed low Pd leaching.

Graphical abstract: Accessing stable zirconium carboxy-aminophosphonate nanosheets as support for highly active Pd nanoparticles

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Article information

DOI
https://doi.org/10.1039/C5CC06292F
Article type
Communication
Submitted
27 Jul 2015
Accepted
03 Sep 2015
First published
03 Sep 2015

Chem. Commun., 2015,51, 15990-15993

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Accessing stable zirconium carboxy-aminophosphonate nanosheets as support for highly active Pd nanoparticles

F. Costantino, R. Vivani, M. Bastianini, L. Ortolani, O. Piermatti, M. Nocchetti and L. Vaccaro, Chem. Commun., 2015, 51, 15990 DOI: 10.1039/C5CC06292F

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