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Issue 8, 2016
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Dodecanuclear 3d/4f-metal clusters with a ‘Star of David’ topology: single-molecule magnetism and magnetocaloric properties

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Abstract

A family of interwoven molecular inorganic knots, shaped like the ‘Star of David’, was prepared by the employment of naphthalene-2,3-diol in 3d/4f-metal cluster chemistry; the isoskeletal dodecanuclear compounds exhibit slow relaxation of the magnetization and magnetocaloric properties, depending on the metal ion.

Graphical abstract: Dodecanuclear 3d/4f-metal clusters with a ‘Star of David’ topology: single-molecule magnetism and magnetocaloric properties

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Article information


Submitted
12 Nov 2015
Accepted
25 Nov 2015
First published
25 Nov 2015

Chem. Commun., 2016,52, 1693-1696
Article type
Communication

Dodecanuclear 3d/4f-metal clusters with a ‘Star of David’ topology: single-molecule magnetism and magnetocaloric properties

D. I. Alexandropoulos, L. Cunha-Silva, G. Lorusso, M. Evangelisti, J. Tang and T. C. Stamatatos, Chem. Commun., 2016, 52, 1693
DOI: 10.1039/C5CC09385F

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