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Issue 98, 2015
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l-Aspartate links for stable sodium metal–organic frameworks

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Abstract

Metal–organic frameworks (MOFs) based purely on sodium are rare, typically due to large numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker with flexible carboxylate groups to enhance framework stability. We report two new air-stable sodium MOFs, MOF-705 and MOF-706, comprising 2D sodium oxide sheets.

Graphical abstract: l-Aspartate links for stable sodium metal–organic frameworks

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Publication details

The article was received on 10 Sep 2015, accepted on 30 Sep 2015 and first published on 30 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC07578E
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Chem. Commun., 2015,51, 17463-17466

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    L-Aspartate links for stable sodium metal–organic frameworks

    P. Siman, C. A. Trickett, H. Furukawa and O. M. Yaghi, Chem. Commun., 2015, 51, 17463
    DOI: 10.1039/C5CC07578E

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