Issue 91, 2015
From the journal:

Chemical Communications

Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination†

Emma Bresó-Femenia,ab   Cyril Godard,c   Carmen Claver,cd   Bruno Chaudret*b  and  Sergio Castillón*a  

* Corresponding authors

a Departament de Química Analítica i Orgànica, Universitat Rovira I Virgili, C/ Marcel.lí Domingo s/n, 43007 Tarragona, Spain
E-mail: sergio.castillon@urv.cat

b Laboratoire de Physique et Chimie des Nano Objets, LPCNO, UMR 5215 INSA-UPS-CNRS, Université de Toulouse, Institut National des Sciences Appliquées, 135 avenue de Rangueil, 31077 Toulouse, France
E-mail: bruno.chaudret@insa-toulouse.fr

c Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, C/ Marcel.lí Domingo s/n, 43007 Tarragona, Spain

d Centre de Tecnologia Química de Catalunya (CTQC), C/ Marcel.lí Doming s/n, 43007 Tarragona, Spain

Abstract

Phenyl rings in phenyl- or phenyl-alkylphosphines are selectively deuterated at the ortho position using Ru/PVP nanoparticles, while are fully reduced in the case of arylphosphine oxide derivatives and do not react in the case of arylphosphite. This different behavior provides information about the coordination mode of each ligand.

Graphical abstract: Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination

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Article information

DOI
https://doi.org/10.1039/C5CC06984J
Article type
Communication
Submitted
19 Aug 2015
Accepted
11 Sep 2015
First published
11 Sep 2015

Chem. Commun., 2015,51, 16342-16345

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Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination

E. Bresó-Femenia, C. Godard, C. Claver, B. Chaudret and S. Castillón, Chem. Commun., 2015, 51, 16342 DOI: 10.1039/C5CC06984J

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