The 5′-end N-sugar puckering is currently believed to govern the intramolecular dinucleotide stacking. We demonstrate that if this 5′-conformation is indeed important in shaping up dinucleotide structures, the 3′-end sugar conformation can either potentiate or cancel the stacking capacity induced by the 5′-end N-sugar conformation.
J. Jakhlal, S. Coantic-Castex, C. Denhez, C. Petermann, A. Martinez, D. Harakat, D. Guillaume and P. Clivio, Chem. Commun., 2015, 51, 12381 DOI: 10.1039/C5CC04212G
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