Issue 45, 2015
From the journal:

Chemical Communications

VCD spectroscopy as an excellent probe of chiral metal complexes containing a carbon monoxide vibrational chromophore†

Marco Fusè,‡a   Giuseppe Mazzeo,‡b   Giovanna Longhi,bc   Sergio Abbate,bc   Daniele Zerla,a   Isabella Rimoldi,a   Alessandro Continia  and  Edoardo Cesarotti*a  

* Corresponding authors

a Dipartimento di Scienze Farmaceutiche, Università di Milano Via Golgi 19, 20133 Milano, Italy
E-mail: edoardo.cesarotti@unimi.it

b Dipartimento di Medicina Molecolare e Traslazionale, Università di Brescia, Viale Europa 11, 25123 Brescia, Italy

c CNISM Consorzio Nazionale Interuniversitario per le Scienze Fisiche della Materia, Via della Vasca Navale, 84, 00146 Roma, Italy

Abstract

Vibrational circular dichroism, VCD, gives evidence that the carbon monoxide chromophore in a heteroleptic cyclopentadienyl Ru(II)-carbonyl complex is very sensitive to the chirality of the metal centre and becomes an excellent probe to define the configuration of chiral metal complexes.

Graphical abstract: VCD spectroscopy as an excellent probe of chiral metal complexes containing a carbon monoxide vibrational chromophore

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Article information

DOI
https://doi.org/10.1039/C5CC02170G
Article type
Communication
Submitted
13 Mar 2015
Accepted
30 Apr 2015
First published
30 Apr 2015

Chem. Commun., 2015,51, 9385-9387

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VCD spectroscopy as an excellent probe of chiral metal complexes containing a carbon monoxide vibrational chromophore

M. Fusè, G. Mazzeo, G. Longhi, S. Abbate, D. Zerla, I. Rimoldi, A. Contini and E. Cesarotti, Chem. Commun., 2015, 51, 9385 DOI: 10.1039/C5CC02170G

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