Issue 46, 2015
From the journal:

Chemical Communications

A new surfactant-introduction strategy for separating the pure single-phase of metal–organic frameworks†

Jun Zhao,ab   Yenan Wang,a   Wenwen Dong,a   Yapan Wu,a   Dongsheng Li,*a   Bin Liu*c  and  Qichun Zhang*b  

* Corresponding authors

a College of Materials and Chemical Engineering, Hubei Provincial Collaborative Innovation Center for New Energy Microgrid, China Three Gorges University, Yichang 443002, P. R. China
E-mail: lidongsheng1@126.com

b School of Materials Science and Engineering, & Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 639798, Singapore
E-mail: qczhang@ntu.edu.sg

c Key Laboratory of Synthetic and Natural Functional Molecule Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069, P. R. China
E-mail: liubin@nwu.edu.cn

Abstract

By introducing different surfactants into a reaction system, two previous mixed-phase Ni(II)–MOFs constructed from an undeveloped pyridyl-tetracarboxylate and Ni(II) salts were successfully isolated to obtain two pure products. Compound 1 exhibits a 3D H-bonded network with (3,8)-connected {4.52}2{42.56.614.72.84} topology, while 2 features a 3D 2-fold interpenetrating framework with a self-penetrating (3,4,4)-connected {62.103.12}{63}2{64.8.10}2 topological net.

Graphical abstract: A new surfactant-introduction strategy for separating the pure single-phase of metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C5CC02043C
Article type
Communication
Submitted
10 Mar 2015
Accepted
24 Apr 2015
First published
27 Apr 2015

Chem. Commun., 2015,51, 9479-9482

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A new surfactant-introduction strategy for separating the pure single-phase of metal–organic frameworks

J. Zhao, Y. Wang, W. Dong, Y. Wu, D. Li, B. Liu and Q. Zhang, Chem. Commun., 2015, 51, 9479 DOI: 10.1039/C5CC02043C

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