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Issue 36, 2015
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(E)-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases

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Abstract

An unprecedented base-promoted direct olefination of aryl alcohols with sulfones via a Julia-type reaction has been described. No extra reductants are needed for Julia reaction since alcohols work as double sources of aldehydes and the hydride. Generally high yields were given for both terminal and highly (E)-selective internal olefins.

Graphical abstract: (E)-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases

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Publication details

The article was received on 08 Mar 2015, accepted on 25 Mar 2015 and first published on 25 Mar 2015


Article type: Communication
DOI: 10.1039/C5CC01965F
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Citation: Chem. Commun., 2015,51, 7729-7732
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    (E)-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases

    C. Yao, Q. Li, M. Wang, X. Ning and Y. Kang, Chem. Commun., 2015, 51, 7729
    DOI: 10.1039/C5CC01965F

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